86. Mortelliti, M. J.; Patel, M. Y.; Dempsey, J. L. Ultrathin Tin-doped Titanium Oxide by Atomic Layer Deposition on a Mesoporous Substrate: Physical/Electronic Structure, Spectroelectrochemistry, and Interfacial Charge TransferJ. Phys. Chem. C 2022In Press.

85. Kessler, M. L.; Kelm, J. E.; Starr, H. E.; Cook, E. N.; Miller, J. D.; Rivera, N. A.; Hsu-Kim, H.;  Dempsey, J. L. Unraveling Changes to PbS Nanocrystal Surfaces Induced by Thiols. Chemistry of Materials 202234, 1710-1721.

84. Patel, M. Y.; Mortelliti, M. J.; Dempsey, J. L. A Compendium and Meta-Analysis of Flatband Potentials for TiO2, ZnO, and SnO2 Semiconductors in Aqueous MediaChemical Physics Reviews 2022, 3, 011303.

*Featured Article

83. Hartley, C. L.; Kessler, M. L.; Dones Lassalle, C. Y.; Camp, A. M.; Dempsey, J. L. Effects of Ligand Shell Composition on Surface Charging in PbS Quantum Dots. Chem. Mater. 2021, 33, 8612-8622.

82. Mortelliti, M. J.; Huang, C.-W.; Atkin, J. M.; Dempsey, J. L. Mixed Tin-Titanium Oxides by Atomic Layer Deposition on Planar Substrates: Physical and Electronic Structure. Appl. Surf. Sci. 2021, 573, 151564.

81. Stratakes, B. M.; Dempsey, J. L.; Miller, A. J. M. Determining the Overpotential of Electrochemical Fuel Synthesis Mediated by Molecular Catalysts: Recommended Practices, Standard Reduction Potentials, and Challenges. ChemElectroChem 2021, 8, 4161-4180.

*Invited Contribution to Special Issue In Memoriam: Prof. Jean-Michel Savéant

80. Rodriguez, T. M.; Deegbey, M.; Jakubikova, E.; Dempsey, J. L. The Ligand-to-Metal Charge Transfer Excited State of [Re(dmpe)3]2+. Photosynth. Res. 2021 ASAP.

*Invited Contribution to the Photochemistry and Electrochemistry of Natural and Artificial Photosynthesis Special Issue

79. Mortelliti, M. J.; Wang, A. N.; Dempsey, J. L. Interfacial Electron Transfer Through Ultrathin ALD TiOx Layers: A Comparative Study of TiO2/TiOx and SnO2/TiOx Core/Shell Nanocrystals. J. Phys. Chem. C 2021125, 12937–12959.

78. Dempsey, J. L.; Heyer, C. M.; Meyer, G. J. A Vision for Sustainable Energy: The Center for Hybrid Approaches in Solar Energy to Liquid Fuels (CHASE). Electrochem. Soc. Interface 2021, 30, 65-67.

77. Hartley, C. L.; Dempsey, J. L. Revealing the Molecular Identity of Defect Sites on PbS Quantum Dot Surfaces with Redox-Active Chemical Probes. Chem. Mater. 2021, 33, 2655–2665.

76. Kurtz, D. A.; Dhar, D.; Elgrishi, N.; Kandemir, B.; McWilliams, S. F.; Howland, W. C.; Chen, C.-H.; Dempsey, J. L. Redox-Induced Structural Reorganization Dictates Kinetics of Cobalt(III)-Hydride Formation via Proton-Coupled Electron Transfer. J. Am. Chem. Soc. 2021,  143, 3393–3406.

*Featured in JACS Spotlights
*Featured in JACS Video Bytes.
*Highlighted in Matter: Zurakowski J. A.; Dover, M. W. A Proton passing game: A relay across the goal line. Matter 2021, 4, P2598–2600.

75. Hartley, C. L.; Kessler, M. L.; Dempsey, J. L. Molecular-Level Insight into Semiconductor Nanocrystal Surfaces. J. Am. Chem. Soc.  2021, 143, 1251–1266.

*Invited Perspective

74. Huffman, B. L.; Lee, K. J.; Geer, A. M.; McKeown, B. A.; Jia, X.; Dickie, D. A.; Gunnoe, T. B.; Dempsey, J. L. Role of Axial Ligation in Gating the Reactivity of Dimethylplatinum(III) Diimine Radical Cations. Organometallics 2021, 40, 333–345.

73. Bangle, R. E.; Mortelliti, M. J.; Troian-Gautier, L.; Dempsey, J. L.; Meyer, G. J. Tunneling and Thermally Activated Electron Transfer in Dye-Sensitized SnO2/TiO2 Core/Shell Nanostructures. J. Phys. Chem. C 2020, 124, 25148–25159.

72. Taggart, A. D.; Evans, J. M.; Lee, L.; Lee, K. J.; Dempsey, J. L.; Kanai, Y.; Cahoon, J. F. Enabling Aqueous NiO Photocathodes by Passivating Surface Sites that Facilitate Proton-Coupled Charge TransferACS Appl. Energy Mater. 2020, 11, 10702–10713.

71. Lee, K. J.; Lodaya, K. M.; Gruninger, C. T.; Rountree, E. S.; Dempsey, J. L. Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes. Chem. Sci. 2020, 11, 9836-9851.

*Part of the themed collection: 2020 Chemical Science HOT Article Collection
*Featured on the Chemical Science Blog

70. Dhar, D.; McKenas, C. G.; Huang, C.-W.; Atkin, J. M.; Dempsey, J. L.; Lockett, M. R. Quantitative effects of disorder on chemically modified amorphous carbon electrodesACS Appl. Energy Mater. 2020, 3, 8038-8047.

69. Buonsanti, R.; Buriak, J. M.; Cabana, L.; Cossairt, B. M.; Dasog, M.; Dempsey, J. L.; Grace, A. N.; Kozieg, D.; McElwee-White, L.; Thomas, C.; Yang, J. Y. Checking in with Women Materials Scientists During a Global Pandemic: May 2020Chem. Mater. 202032, 4859-4862.

68. Huang, T.; Rodriguez, T. M.; Gruninger, C. T.; Kurtz, D. A.; Jordan, A. M.; Chen, C.-H.; Dempsey, J. L. Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced FormationOrganometallics 2020, 39, 1730–1743

67. Kessler, Melody L.; Dempsey, J. L. Mapping the Topology of PbS Nanocrystals through Displacement Isotherms of Surface-Bound Metal Oleate ComplexesChem. Mater. 2020, 32, 2561–2571.

66.  Barrett, S. M.; Stratakes, B. M.; Chambers, M. B.; Kurtz, D. A.; Pitman, C. L.; Dempsey, J. L.; Miller, A. J. M. Mechanistic Basis for Tuning Iridium Hydride Photochemistry from H2 Evolution to Hydride Transfer Hydrodechlorination. Chem. Sci. 2020, 11, 6442-6449.

*Invited Contribution to the Chemical Science 10th Anniversary Special Issue
*Part of the themed collection: 2020 Chemical Science HOT Article Collection

Graphical abstract: Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

65. Lee, K. J.; Gruninger, C. T.; Lodaya, K. M.; Qadeer, S.; Griffith, B. E.; Dempsey, J. L. Analysis of multielectron, multistep homogeneous catalysis by rotating disc electrode voltammetry: Theory, application, and obstaclesAnalyst 2020, 145, 1258-1278.

*Invited Contribution to the Versatile Electrochemical Approaches for Sensing, Biology, and Energy Special Issue

64. Kurtz, D. A.; Dempsey, J. L. Proton-Coupled Electron Transfer Kinetics for the Photoinduced Generation of a Cobalt(III)-Hydride Complex. Inorg. Chem.  2019, 58, 16510-16517.

63. Cossairt, B. M., Dempsey, J. L.; Young, E. R. The Chemistry Women Mentorship Network (ChemWMN): A Tool for Creating Critical Mass in Academic ChemistryInorg. Chem201958, 12493-12496. Published simultaneous as ACS Cent. Sci. 2019, 5, 1625–1629. Chem. Mater. 2019, 31, 8239–8242.

62. Dempsey, J. L. and Lancaster, K. M. Celebrating the Year of the Periodic Table: Emerging Investigators in Inorganic Chemistry. Inorg. Chem. 201958, 10433-10435.

61. Wang, D.; Niu, F.; Mortelliti, M. J.; Sheridan, M. V.; Sherman, B. D.; Zhu, Y.; McBride, J. R.; Dempsey, J. L.; Shen, S.; Dares, C. J.; Li, F.; Meyer, T. J. A stable dye-sensitized photoelectrosynthesis cell mediated by a NiO overlayer for water oxidationProc. Natl. Acad. Sci. USA 2020, 117, 12564-12571.

60. Mortelliti, M. J.; Wang, A. N.; Dempsey, J. L. Atomic Layer Deposition of SnOx onto Mesoporous, Nanocrsytalline TiO2 and SnO2 Thin FilmsPolyhedron 2019171, 433-447.

*Invited Contribution to the Women with MOxy: Metal Oxide Chemistry from Female Investigators Special Issue

59. Lennox, J. C.; Danilov, E. O.; Dempsey, J. L. Delayed photoacidity produced through the triplet-triplet annihilation of a neutral pyranine derivativePhysical Chemistry Chemical Physics 2019, 21, 16353-16358.

58. Lee, K. J.; McCarthy, B. D.; Dempsey, J. L. On Decomposition, degradation, and voltammetric deviation: the electrochemist’s field guide to identifying precatalyst transformationChemical Society Reviews 2019, 48, 2927-2945.

57. Dempsey, J. L. How a highly driven reaction hits the brakes. Science 2019, 364, 436–437.

56. Rountree, E. S.; McCarthy, B. D.; Dempsey, J. L. Decoding Proton-Coupled Electron Transfer with Potential–pKa Diagrams: Applications to CatalysisInorganic Chemistry 2019, 10, 6647-6658.

55. Hartley, C. L.; Dempsey, J. L. Electron-Promoted X-Type Ligand Displacement at CdSe Quantum Dot SurfacesNano Letters 201919, 1151–1157.

54. Dong, Q.; Liu, H.; Hara, Y.; Starr, H. E.; Dempsey, J. L.; Lopez, R. Impact of Background Oxygen Pressure on the Pulsed-Laser Deposition of ZnO Nanolayers and on Their Corresponding Performance as Electron Acceptors in PbS Quantum-Dot Solar Cells.  ACS Applied Nano Materials 2019, 2, 767–777.

53. Huang, T.; Rountree, E. S.; Traywick, A. P.; Bayoumi, M.; Dempsey, J. L. Switching between Stepwise and Concerted Proton-Coupled Electron Transfer Pathways in Tungsten Hydride ActivationJ. Am. Chem. Soc. 2018, 140, 14655–14669.

52. Kessler, M. L.; Starr, H. E.; Knauf, R. R.; Rountree, K. J.; Dempsey, J. L. Exchange equilibria of carboxylate-terminated ligands at PbS nanocrystal surfacesPhys. Chem. Chem. Phys. 2018, 20, 23649–23655.

51. Lee, K. J.; Dempsey, J. L. PCET2018 Highlights: Proton-Coupled Electron Transfers for Energy Conversion Strategies. ACS Energy Lett. 2018, 3, 2477–2479.

50. Han, Y.; Dillon, R. J.; Flynn, C. J.; Rountree, E. S.; Alibabaei, L.; Cahoon, J. F.; Papanikolas, J. M.; Dempsey, J. L. Interfacial Electron Transfer Yields in Dye-Sensitized NiO Photocathodes Correlated to Excited-State Dipole Orientation of Ruthenium ChromophoresCan. J. Chem. 2018, 96, 865–874.

*Invited contribution to the Electron Donor Acceptor Interactions Thematic Issue

49. Kurtz, D. A.; Brereton, K. R.; Ruoff, K. P.; Tang, H. M.; Felton, G. A. N.; Miller, A. J. M.; Dempsey, J. L. Bathochromic Shifts in Rhenium Carbonyl Dyes Induced through Destabilization of Occupied OrbitalsInorg. Chem. 2018, 57, 5389-5399.

 

48. Elgrishi, N.; Rountree, K. J.; McCarthy, B. D.; Rountree, E. S.; Eisenhart, T. T.; Dempsey, J. L. A Practical Beginner’s Guide to Cyclic Voltammetry. J. Chem. Ed. 2018, 95, 197-206.

*ACS Editor’s Choice

*Most Read Articles in Journal of Chemical Education List

 

47. Lennox, J. C.; Dempsey, J. L. Influence of Proton Acceptors on the Proton-Coupled Electron Transfer Reaction Kinetics of a Ruthenium-Tyrosine ComplexJ. Phys. Chem. B 2017, 121, 10530–10542.

 

46. Lee, K. J.; Dempsey, J. L. When Electrochemistry Met Methane: Rapid Catalyst Oxidation Fuels Hydrocarbon FunctionalizationACS Cent. Sci. 2017, 3, 1137–1139. 

45. Dempsey, J. L.; Hartings, M. R. Hop to ItBiochemistry201756, 5623–5624.

 

44. McCarthy, B. D.; Dempsey, J. L.  Cultivating Advanced Technical Writing Skills through a Graduate-Level Course on Writing Research ProposalsJ. Chem. Ed. 2017, 94, 696–702.

JChemEdTOC

 

43. Lennox, J. C.; Kurtz, D. A.; Huang, T.; Dempsey, J. L. Excited-State Proton-Coupled Electron Transfer: Different Avenues for Promoting Proton/Electron Movement with Solar Photons. ACS Energy Lett. 2017, 2, 1246–1256.

*Invited Review

ACSEnergyLettTOC

 

42. Lee, K. J.; Elgrishi, N. E.; Kandemir, B.; Dempsey, J. L. Applications of electrochemical and spectroscopic methods for evaluating molecular electrocatalystsNat. Rev. Chem. 20171, 0039.

*Invited Review

TOC

 

41. Lee, K. J.; McCarthy, B. D.; Rountree, E. S.; Dempsey, J. L. Identification of an Electrode-Adsorbed Intermediate in the Catalytic Hydrogen Evolution Mechanism of a Cobalt Dithiolene Complex. Inorg. Chem. 2017, 56, 1988–1998.

*Featured in Synthetic Chemistry Addressing Challenges in Energy and the Environment Virtual Issue

toc

 

40.  McCarthy, B. D.; Dempsey, J. L. Decoding Proton-Coupled Electron Transfer with Potential-pKa Diagrams. Inorg. Chem. 2017, 56, 1225–1231.

E-pKa TOC graphic 1

 

39. Elgrishi, N.; Kurtz, D. A.; Dempsey, J. L. Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts. J. Am. Chem. Soc. 2017, 139, 239–244.

elgrishi-toc

 

38. Eisenhart, T. T.; Howland, W. C.; Dempsey, J. L. Proton-Coupled Electron Transfer Reactions with Photometric Bases Reveal Free Energy Relationships for Proton Transfer. J. Phys. Chem. B 2016, 120, 7896–7905.

TOC no line

 

37. Knauf, R. R.; Lennox, J. C.; Dempsey, J. L. Quantifying Ligand Exchange Reactions at CdSe Nanocrystal Surfaces. Chem. Mater. 201628, 4762–4770.

TOC

 

36. Call, R. W.; Alibabaei, L.; Dillon, R. J.; Knauf, R. R.; Nayak, A.; Dempsey, J. L.; Papanikolas, J. M.; Lopez, R. Growth and Post-Deposition Treatments of SrTiOFilms for Dye-Sensitized Photoelectrosynthesis Cell Applications. ACS Appl. Mater. Interfaces 20168, 12282–12290.

am-2016-01289d_0007

 

 35. Elgrishi, N.; McCarthy, B. D.; Rountree, E. S.; Dempsey, J. L. Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes. ACS Catalysis 2016, 6, pp 3644–3659.

*Invited Perspective

TOC idea_NE_V3-01

 

34. Rountree, E. S.; Dempsey, J. L. Reactivity of Proton Sources with a Nickel Hydride Complex in Acetonitrile: Implications for the Study of Fuel Forming Catalysts. Inorg. Chem. 2016, 55 , 5079–5087.

*Featured in Synthetic Chemistry Addressing Challenges in Energy and the Environment Virtual Issue

TOC_graphic2

 

33. Rountree, E. S.; Martin, D. J.; McCarthy, B. D.; Dempsey, J. L. Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst. ACS Catalysis. 2016, 6, 3326–3335.

GA Wheels

 

32. Hara, Y.; Gadisa, A.; Fu, Y.; Garvey, T.; Vrouwenvelder, K. T.; Miller, C. W.; Dempsey, J. L.; Lopez, R. Gains and Losses in PbS Quantum Dot Solar Cells with Submicron Periodic Grating Structures. J. Phys. Chem. C. 2016, 120, 8005–8013.

jp-2016-01498f_0011

 

31. Martin, D. J.; McCarthy, B. D.; Rountree, E. S.; Dempsey, J. L. Qualitative Extension of the EC’ Zone Diagram to a Molecular Catalyst for a Multi-Electron, Multi-Substrate Electrochemical Reaction. Dalton Trans. 2016, 45, 9970-9976.

*Invited Contribution to the ‘New Talent: Americas’ Special Issue

Graphical Abstract

 

30. Dempsey, J. L. Ligand steals spotlight from metal to orchestrate hydrogen production. Proc. Natl. Acad. Sci. USA. 2016, 113, 478-479.

29. Martin, D. J.; McCarthy, B. D.; Piro, N. A.; Dempsey, J. L. Synthesis and Electrochemical Characterization of a Tridentate Schiff-base Ligated Fe(II) Complex. Polyhedron 2016, 114, 200–204.

*Invited Contribution to the ‘Undergraduate Research in Inorganic Chemistry’ Special Issue

Graphical Abstract 3

 

28. Knauf, R. R.; Kalanyan, B.; Parsons, G. N.; Dempsey, J. L. Charge Recombination Dynamics in Sensitized SnO2/TiO2 Core/Shell Photoanodes. J. Phys. Chem. C. 2015, 119, 28353–28360.

Core Shell TOC-01

 

27. Rountree, E. S.; Dempsey, J. L. Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with pKa for Mechanistic Investigations of a Nickel-Based Hydrogen Evolution Catalyst. J. Am. Chem. Soc. 2015, 137, 13371–13380.

*Featured in the 2017 JACS Young Investigator Virtual Issue

erictoc

 

26. McCarthy, B. D.; Donley, C. L.; Dempsey, J. L. Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(II) coordination complex. Chem. Sci. 2015, 6, 2827-2834.

TOC graphic design 2-01

 

25. Gadisa, A.; Hara, Y.; Fu, Y.; Vrouwenvelder, K.; Dempsey, J. L.; Samulski, E.; Lopez, R. Disparity in Optical Charge Generation and Recombination Processes in Upright and Inverted PbS Quantum Dot Solar Cells. J. Phys. Chem. C. 2015. 119, 4606–4611.

jp-2014-12305x_0006

 

24. Dempsey, J. L. Proton-coupled electron transfer: Metal hydrides find the sweet spot. Nature Chem. 2015, 7, 101-102.

nchem.2162-f1

 

23. Martin, D. J.; McCarthy, B. D.; Donley, C. L.; Dempsey, J. L. Electrochemical Hydrogenation of a Homogeneous Nickel Complex to Form a Surface Adsorbed Hydrogen-Evolving Species. Chem. Commun. 2015, 51, 5290-5293.

*Featured in the 2015 Emerging Investigators Issue

Daniels TOC

 

22. Rountree, E. S.; McCarthy, B. D.; Eisenhart, T. T.; Dempsey, J. L. Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry. Inorg. Chem. 2014, 53, 9983–10002.

*Viewpoint Article

*Most Read Articles in Inorg. Chem. list

Ic viewpoint

 

21. Eisenhart, T. T.; Dempsey, J. L. Photo-Induced Proton-Coupled Electron Transfer Reactions of Acridine Orange: Comprehensive Spectral and Kinetics Analysis. J. Am Chem. Soc. 2014, 136, 12221–12224.

*Featured on JACS coverjacsat-v136i035-2_Page_1

*Featured in JACS Spotlights

WebsiteTOC

 

20. McCarthy, B. D.; Martin, D. J.; Rountree, E. S.; Ullman, A. C.; Dempsey, J. L. Electrochemical Reduction of Brønsted Acids by Glassy Carbon in Acetonitrile – Implications for Electrocatalytic Hydrogen Evolution. Inorg. Chem. 2014, 53, 8350–8361.

*Highlighted in the 2015 Inorg. Chem. − J. Am. Chem. Soc. ‘Inorganic Chemistry Driving the Energy Sciences’ virtual issue.

GC TOC

 

19. Nayak, A.; Knauf, R. R.; Hanson, K.; Alibabaei, L.; Concepcion, J. J.; Ashford, D. L.; Dempsey, J. L.; Meyer, T. J. Synthesis and Photophysical Characterization of Porphyrin and Porphyrin-Ru(II) Polypyridyl Chromophore-Catalyst Assemblies on Mesoporous Metal Oxides. Chem. Sci. 2014, 5, 3115-3119.

ChemSci_2014

 

18. Knauf, R. R.; Brennaman, M. K.; Alibabaei, L.; Norris, M. R.; Dempsey, J. L. Revealing the Relationship Between Semiconductor Electronic Structure and Electron Transfer Dynamics at Metal Oxide-Chromophore Interfaces. J. Phys. Chem. C. 2013, 117, 25259-25268.

JPCC_2013

 

Prior to UNC

17. McKone, J. R; Ardo, S.; Blakemore, J. D.; Bracher, P. D.; Dempsey, J. L.; Darnton, T. V.; Hansen, M. C.; Harman, W. H.; Rose, M. R.; Walter, M. G.; Dasgupta, S.; Winkler, J. R.; Gray, H. B. The Solar Army: A Case Study in Outreach Based on Solar Photoelectrochemistry. Rev. Adv. Sci. Eng. 2014, 3, 288-303.

16. Bhattacharjee, A.; Chavarot-Kerlidou, M.; Dempsey, J. L.; Gray, H. B.; Fujita, E.; Fontecave, M.; Artero, V.; Arantes, G. M.; Field, M. J. Theoretical Modeling of Low Energy Electronic Transitions in Reduced Cobaloximes. ChemPhysChem. 2014, 15, 2951-2958.

15. Bradshaw, L. R.; May, J. W.; Dempsey, J. L.; Li, X.; Gamelin, D. R. Ferromagnetic excited-state Mn2+ dimers in Zn1-xMnxSe quantum dots observed by time-resolved magnetophotoluminescence. Phys. Rev. B. 2014, 89, 115312.

14. White, M. A.; Dempsey, J. L.; Carroll, G. M.; Gallagher, J. D.; Gamelin, D. R. Photoconductive ZnO films with embedded quantum dot or ruthenium dye sensitizers. APL Mater. 2013, 1, 032107.

13. Dempsey, J. L.; Winkler, J. R.; Gray, H. B. Solar Fuels: Approaches to Catalytic Hydrogen Evolution. in Comprehensive Inorganic Chemistry II. ed. V. W. W. Yam,  Elsevier, Waltham, MA.  2013. vol. 8, ch. 15, pp. 553-565.

12. Valdez, C. N.;  Dempsey, J. L.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. Catalytic Hydrogen Evolution from a Covalently Linked Dicobaloxime. Proc. Natl. Acad. Sci. USA. 2012, 109, 15589-15593.

11. Dempsey, J. L.; Winkler, J. R.; Gray, H. B. Redox Reactivity of Photogenerated Osmium(II) Complexes. Dalton Trans. 2011, 40, 10633-10636.

10. Dempsey, J. L.; Winkler, J. R.; Gray, H. B. Mechanism of H2 Evolution by a Photogenerated Hydridocobaloxime.J. Am. Chem. Soc. 2010, 132, 16774–16776.

9. Dempsey, J. L.; Winkler, J. R.; Gray, H. B. Proton-Coupled Electron Flow in Protein Redox Machines. Chem. Rev. 2010, 110, 7024–7039.

8. Dempsey, J. L.; Winkler, J. R.; Gray, H. B. Kinetics of Electron Transfer Reactions of H2 Evolving Cobalt Diglyoxime Catalysts. J. Am. Chem. Soc. 2010, 132, 1060–1065.

7. Peters, J. C.; Miller, A. J. M.; Dempsey, J. L. “Emissive Monomeric Metal Complexes.” U.S. Patent 7,683,183 B2, 2010.

6. Dempsey, J. L.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. Hydrogen Evolution Catalyzed by Cobaloximes. Acc. Chem. Res. 2009, 42, 1995–2004.

5. Miller, A. J. M.; Dempsey, J. L.; Peters, J. C. Long-Lived and Efficient Emission from Mononuclear Amidophosphine Complexes of Copper. Inorg. Chem. 2007, 46, 7244–7246.

4. Esswein, A. J.; Dempsey, J. L.; Nocera, D. G. A Rh(II)-Au(II) Bimetallic Core with a Direct Metal-Metal Bond. Inorg. Chem. 2007, 46, 2362–2364.

3. Dempsey, J. L.; Esswein, A. J.; Manke, D. R.; Rosenthal, J.; Soper, J. D.; Nocera, D. G. Molecular Chemistry of Consequence to Renewable Energy. Inorg. Chem. 2005, 44, 6879–6892.

2. Rosenthal, J.; Bachman, J.; Dempsey, J. L.; Esswein, A. J.; Gray, T. G.; Hodgkiss, J. M.; Manke, D. R.; Luckett, T. D.; Pistorio, B. J.; Veige, A. S.; Nocera, D. G. Oxygen and Hydrogen Photocatalysis by Two-Electron Mixed-Valence Coordination Compounds. Coord. Chem. Rev. 2005, 249, 1316–1326.

1. Wu, N.; Dempsey, J.; Yehl, P. M.; Dovletoglou, A.; Ellison, D.; Wyvratt, J. Practical aspects of fast HPLC separations for pharmaceutical process development using Monolithic Columns. Anal. Chim. Acta 2004, 523, 149–156.